Abstract
We have measured the viscometric functions of mono- and bimodal noncolloidal suspensions of poly (methyl methacrylate) spheres in a density-matched aqueous Newtonian suspending fluid using parallel-plate and cone-and-plate rheometry for particle volume fractions in the range of 0.20-0.50. Cone-and-plate normal stress measurements employed the method of Marsh and Pearson, in which there is a finite gap between the cone tip and the plate. The monodisperse suspensions showed an unexpected particle size dependence of the viscometric functions, with the viscosity increasing with decreasing particle size. Normal stresses were very small in magnitude and difficult to measure at volume fractions below 0.30. At higher concentrations, N-2 was negative and much larger in magnitude than N-1, for which the algebraic sign was positive over most of the shear rate range for the monodisperse suspensions but indeterminate and possibly negative for the bimodal suspensions. The normal stresses were insensitive to bidispersity when plotted as functions of the shear stress at each volume fraction. (C) 2016 The Society of Rheology.
