-
Dichloridobis{N,N-diethyl-4-[(pyridin-2yl-kappa N)diazenyl]aniline}zinc
- Back
Metadata
Document Title
Dichloridobis{N,N-diethyl-4-[(pyridin-2yl-kappa N)diazenyl]aniline}zinc
Author
Leesakul N, Pakawatchai C, Saithong S, Tantirungrotechai Y, Kwanplod K
Name from Authors Collection
Affiliations
Prince of Songkla University; Prince of Songkla University; National Science & Technology Development Agency - Thailand; National Nanotechnology Center (NANOTEC)
Type
Article
Source Title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN
1600-5368
Year
2011
Volume
67
Issue
3
Open Access
gold, Green Published
Publisher
WILEY-BLACKWELL
DOI
10.1107/S1600536811022884
Format
Abstract
In the title complex, [ZnCl2(C15H18N4)(2)], the Zn-II cation is coordinated by two N atoms from the pyridine rings of two unidentate N,N-diethyl-4-[(pyridin-2-yl)diazenyl]aniline ligands and two Cl atoms, resulting in a distorted tetrahedral geometry. The ligands are mutually transoid with respect to the metal atom. Weak intermolecular C-H center dot center dot center dot Cl hydrogen bonds and pi-pi interactions, with centroid-centroid distances of 3.8452 (14) and 3.9932 (14) angstrom, are found in the crystal packing.
Funding Sponsor
Center for Innovation in Chemistry (PERCH-CIC); Commission on Higher Education; Ministry of Education; National Nanotechnology Center (NANOSIM); Thailand Research Fund [RSA-5180010]
License
CC-BY
Rights
Authors
Publication Source
WOS